| Nr. | Name | Date of Birth | Position | Clubs | Height |
|---|---|---|---|---|---|
| 1 | Claudio BRAVO | 13/04/1983 | GK | Real Sociedad (ESP) | 183 |
| 2 | Ismael FUENTES | 04/08/1981 | DF | Univ. Catolica (CHI) | 181 |
| 3 | Waldo PONCE | 04/12/1982 | DF | Univ. Catolica (CHI) | 183 |
| 4 | Mauricio ISLA | 12/06/1988 | DF | Udinese (ITA) | 177 |
| 5 | Pablo CONTRERAS | 11/09/1978 | DF | PAOK (GRE) | 178 |
| 6 | Carlos CARMONA | 21/02/1987 | MF | Reggina (ITA) | 179 |
| 7 | Alexis SANCHEZ | 19/12/1988 | FW | Udinese (ITA) | 168 |
| 8 | Arturo VIDAL | 22/05/1987 | MF | Bayer Leverkusen (GER) | 178 |
| 9 | Humberto SUAZO | 10/05/1981 | FW | Zaragoza (ESP) | 171 |
| 10 | Jorge VALDIVIA | 19/10/1983 | MF | Al Ain (UAE) | 173 |
| 11 | Mark GONZALEZ | 10/07/1984 | FW | CSKA Moscow (RUS) | 175 |
| 12 | Miguel PINTO | 04/07/1983 | GK | Univ. de Chile (CHI) | 180 |
| 13 | Marco ESTRADA | 28/05/1983 | MF | Univ. de Chile (CHI) | 174 |
| 14 | Matias FERNANDEZ | 15/05/1986 | MF | Sporting Lisbon (POR) | 176 |
| 15 | Jean BEAUSEJOUR | 01/06/1984 | FW | America (MEX) | 178 |
| 16 | Fabian ORELLANA | 27/01/1986 | FW | Xerez (ESP) | 168 |
| 17 | Gary MEDEL | 03/08/1987 | DF | Boca Juniors (ARG) | 171 |
| 18 | Gonzalo JARA | 29/08/1985 | DF | West Bromwich Albion (ENG) | 177 |
| 19 | Gonzalo FIERRO | 21/03/1983 | MF | Flamengo (BRA) | 171 |
| 20 | Rodrigo MILLAR | 03/11/1981 | MF | Colo Colo (CHI) | 182 |
| 21 | Rodrigo TELLO | 14/10/1979 | MF | Besiktas (TUR) | 171 |
| 22 | Esteban PAREDES | 01/08/1980 | FW | Colo Colo (CHI) | 179 |
| 23 | Luis MARIN | 18/05/1983 | GK | Union Espanola (CHI) | 186 |
South American qualifying for South Africa ended with Uruguay and Chile making their returns to the top alongside Brazil, Paraguay and Argentina.
