Goals from David Villa and Andres Iniesta earned Spain a 2-1 win over ten-man Chile and a last-16 meeting with Portugal, while the losers also made it through despite defeat.
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| 1 Claudio BRAVO (GK)(C) | (GK)(C) Iker CASILLAS 1 |
| 3 Waldo PONCE | Gerard PIQUE 3 |
| 4 Mauricio ISLA | Carles PUYOL 5 |
| 7 Alexis SANCHEZ | |
| 8 Arturo VIDAL | |
| 10 Jorge VALDIVIA | XAVI 8 |
| 11 Mark GONZALEZ |
(-55')
|
| 13 Marco ESTRADA | Joan CAPDEVILA 11 |
| 15 Jean BEAUSEJOUR |
(-73')
|
| 17 Gary MEDEL | SERGIO RAMOS 15 |
| 18 Gonzalo JARA | Sergio BUSQUETS 16 |
| 12 Miguel PINTO (GK) | (GK) Victor VALDES 12 |
| 23 Luis MARIN (GK) | (GK) Pepe REINA 23 |
| 2 Ismael FUENTES | Raul ALBIOL 2 |
| 5 Pablo CONTRERAS | Carlos MARCHENA 4 |
| 9 Humberto SUAZO |
(+55')
|
| 16 Fabian ORELLANA | Juan MATA 13 |
| 19 Gonzalo FIERRO | Alvaro ARBELOA 17 |
| 20 Rodrigo MILLAR | PEDRO 18 |
| 21 Rodrigo TELLO | Fernando LLORENTE 19 |
| 22 Esteban PAREDES |
(+73')
|
| 6 Carlos CARMONA | DAVID SILVA 21 |
| 14 Matias FERNANDEZ | Jesus NAVAS 22 |
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