Ballack, 36, who retired last October, made the last of his 98 appearances for Germany in February 2010. He captained his country to third at the 2006 World Cup Germany™ and spent four years at Chelsea from 2006 until 2010.
Under the slogan "Ciao Capitano. A world-class evening", Bayern Munich midfielder Schweinsteiger and Real Madrid coach Mourinho are already confirmed with a 'Ballack & Friends' team taking on a World XI.
"Of course I want to play a bit in both teams, but my fitness levels will decide that," said Ballack, who turned down an invitation from the German Football Association to win his 99th cap in the 3-2 friendly against Brazil in August 2011.
Germany coach Joachim Loew has been invited to Ballack's farewell and his former captain hopes he will be there. "I had a successful time with Loew in the national team, even if there was tension at the end," admitted Ballack.